$ openssl s_client -connect <host>:<port> > foo.certJust make sure to substitute the <host> with the DNS name of the host and the <port> with the actual port number. Once you have the foo.cert file, you will need to manually clean up the foo.cert file a little bit, but it works. Here's a quick example:
$ openssl s_client -connect yahoo.com:443 > yahoo.cert depth=0 /serialNumber=2g8aO5wI1bKJ2ZD588UsLvDe3gTbg8DU/C=US/ST=California/L=Sunnyvale/O=Yahoo Inc./CN=www.yahoo.com verify error:num=20:unable to get local issuer certificate verify return:1 depth=0 /serialNumber=2g8aO5wI1bKJ2ZD588UsLvDe3gTbg8DU/C=US/ST=California/L=Sunnyvale/O=Yahoo Inc./CN=www.yahoo.com verify error:num=27:certificate not trusted verify return:1 depth=0 /serialNumber=2g8aO5wI1bKJ2ZD588UsLvDe3gTbg8DU/C=US/ST=California/L=Sunnyvale/O=Yahoo Inc./CN=www.yahoo.com verify error:num=21:unable to verify the first certificate verify return:1 ^C $ $ $ $ $ cat ./yahoo.cert CONNECTED(00000003) --- Certificate chain 0 s:/serialNumber=2g8aO5wI1bKJ2ZD588UsLvDe3gTbg8DU/C=US/ST=California/L=Sunnyvale/O=Yahoo Inc./CN=www.yahoo.com i:/C=US/O=Equifax/OU=Equifax Secure Certificate Authority --- Server certificate -----BEGIN CERTIFICATE----- MIIE6jCCBFOgAwIBAgIDEIGKMA0GCSqGSIb3DQEBBQUAME4xCzAJBgNVBAYTAlVT MRAwDgYDVQQKEwdFcXVpZmF4MS0wKwYDVQQLEyRFcXVpZmF4IFNlY3VyZSBDZXJ0 aWZpY2F0ZSBBdXRob3JpdHkwHhcNMTAwNDAxMjMwMDE0WhcNMTUwNzAzMDQ1MDAw WjCBjzEpMCcGA1UEBRMgMmc4YU81d0kxYktKMlpENTg4VXNMdkRlM2dUYmc4RFUx CzAJBgNVBAYTAlVTMRMwEQYDVQQIEwpDYWxpZm9ybmlhMRIwEAYDVQQHEwlTdW5u eXZhbGUxFDASBgNVBAoTC1lhaG9vICBJbmMuMRYwFAYDVQQDEw13d3cueWFob28u Y29tMIIBIjANBgkqhkiG9w0BAQEFAAOCAQ8AMIIBCgKCAQEA6ZM1jHCkL8rlEKse 1riTTxyC3WvYQ5m34TlFK7dK4QFI/HPttKGqQm3aVB1Fqi0aiTxe4YQMbd++jnKt djxcpi7sJlFxjMZs4umr1eGo2KgTgSBAJyhxo23k+VpK1SprdPyM3yEfQVdV7JWC 4Y71CE2nE6+GbsIuhk/to+jJMO7jXx/430jvo8vhNPL6GvWe/D6ObbnxS72ynLSd mLtaltykOvZEZiXbbFKgIaYYmCgh89FGVvBkUbGM/Wb5Voiz7ttQLLxKOYRj8Mdk TZtzPkM9scIFG1naECPvCxw0NyMyxY3nFOdjUKJ79twanmfCclX2ZO/rk1CpiOuw lrrr/QIDAQABo4ICDjCCAgowDgYDVR0PAQH/BAQDAgTwMB0GA1UdDgQWBBSmrfKs 68m+dDUSf+S7xJrQ/FXAlzA6BgNVHR8EMzAxMC+gLaArhilodHRwOi8vY3JsLmdl b3RydXN0LmNvbS9jcmxzL3NlY3VyZWNhLmNybDCCAVsGA1UdEQSCAVIwggFOgg13 d3cueWFob28uY29tggl5YWhvby5jb22CDHVzLnlhaG9vLmNvbYIMa3IueWFob28u Y29tggx1ay55YWhvby5jb22CDGllLnlhaG9vLmNvbYIMZnIueWFob28uY29tggxp bi55YWhvby5jb22CDGNhLnlhaG9vLmNvbYIMYnIueWFob28uY29tggxkZS55YWhv by5jb22CDGVzLnlhaG9vLmNvbYIMbXgueWFob28uY29tggxpdC55YWhvby5jb22C DHNnLnlhaG9vLmNvbYIMaWQueWFob28uY29tggxwaC55YWhvby5jb22CDHFjLnlh aG9vLmNvbYIMdHcueWFob28uY29tggxoay55YWhvby5jb22CDGNuLnlhaG9vLmNv bYIMYXUueWFob28uY29tggxhci55YWhvby5jb22CDHZuLnlhaG9vLmNvbTAfBgNV HSMEGDAWgBRI5mj5K9KylddH2CMgEE8zmJCf1DAdBgNVHSUEFjAUBggrBgEFBQcD AQYIKwYBBQUHAwIwDQYJKoZIhvcNAQEFBQADgYEAp9WOMtcDMM5T0yfPecGv5QhH RJZRzgeMPZitLksr1JxxicJrdgv82NWq1bw8aMuRj47ijrtaTEWXaCQCy00yXodD zoRJVNoYIvY1arYZf5zv9VZjN5I0HqUc39mNMe9XdZtbkWE+K6yVh6OimKLbizna inu9YTrN/4P/w6KzHho= -----END CERTIFICATE----- subject=/serialNumber=2g8aO5wI1bKJ2ZD588UsLvDe3gTbg8DU/C=US/ST=California/L=Sunnyvale/O=Yahoo Inc./CN=www.yahoo.com issuer=/C=US/O=Equifax/OU=Equifax Secure Certificate Authority --- No client certificate CA names sent --- SSL handshake has read 1392 bytes and written 456 bytes --- New, TLSv1/SSLv3, Cipher is AES256-SHA Server public key is 2048 bit Secure Renegotiation IS NOT supported Compression: NONE Expansion: NONE SSL-Session: Protocol : TLSv1 Cipher : AES256-SHA Session-ID: Session-ID-ctx: Master-Key: 6385A37EF8BA3E886A242E4F835C453BBE6740C2C240BF9C0F80ED7E0586500B87007EB839C57A8E5539C7CF21387C9F Key-Arg : None Start Time: 1358267053 Timeout : 300 (sec) Verify return code: 21 (unable to verify the first certificate) --- closed